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Do some converting first.

688 calories (4.184 Joules/1 calorie)

= 2878.592 Joules

25 ml of water = 25 grams

q(Jolules) = mass * specific heat * (Temp. final - Temp. initial)

2878.592 Joules = 25 grams Water * 4.180 J/gC * (Temp Final - 80C )

2878.592 Joiles = 104.5( Temp. Final) - 8360

11238.592 =104.5(Temp. Final)

107.55 Celsius Final Temperature ( call it 108 C )

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