Atomic absorption is more sensitive to atomic emission when the excitation potential is greater than 3.5eV.
It is especially sensitive for alkali metals.
Spectral interference is more common in atomic emission spectroscopy due to overlapping spectral lines.
Source modulation is employed to distinguish between atomic absorption (an ac signal) and flame emission (a dc signal).
Digest (dissolve) a small portion of the brass in nitric acid. Then test the sample for copper content using an atomic emission or atomic absorption spectrometer.
Analytical instrumentation: a large class of instruments used to analyze materials and to establish the composition. Some examples: spectrophotometers, mass spectrometers, gas chromatographs, potentiometric titrators, ion analyzers, polarographs, coulometers, x-ray spectro-meters, Karl Fischer titrators, atomic absorption spectrometers, fluorimeters and many, many others.
Atomic absorption spectrometry is more sensitive than atomic emission spectrometry.
It is especially sensitive for alkali metals.
Spectral interference is more common in atomic emission spectroscopy due to overlapping spectral lines.
Source modulation is employed to distinguish between atomic absorption (an ac signal) and flame emission (a dc signal).
ICP-MS allows multi-element analysis. It has a longer linear working range so fewer standards for calibration is needed as they can be spaced further apart. ICP-MS also has a higher sensitivity compared to atomic emission spectrometry or atomic absorption spectrometry.
For one thing, atomic absorption equipment is basically a fancier version of flame emission equipment (I'm unaware of any instrument capable of doing AA that can't also do FE), and flame emission doesn't require you to change tubes every time you want to check for another element.
there is no atomic emission from the sun.
Examples: emission spectrometry, flame photometry, atomic absorption, etc.
advantages of atomic emission
Answer- Flames in atomic emission are more sensitive to flame instability because optimum excitation conditions vary widely from element to element. High temperatures are needed for excitation of some elements and low temperatures for others. The region of flame that gives rise to optimum line intensities varies from element to element. Flame is rarely use in atomic emission because atomization is more complete when using a plasma due to the production of high temperatures. Also the plasma helps reduce the ionization interference effects. In flame absorption, after the sample is nebulized by a flow of gaseous oxidant, mixed with a gaseous fuel and carried into the flame it is then atomized. Then some of the atoms in the gas ionize to form cations and electrons. In flame emission the sample is introduce with argon, carries the sample into the flame. The flame is suppose to atomize the sample, while the flow of gas takes the ions and electrons to be detected.
Digest (dissolve) a small portion of the brass in nitric acid. Then test the sample for copper content using an atomic emission or atomic absorption spectrometer.
Analytical instrumentation: a large class of instruments used to analyze materials and to establish the composition. Some examples: spectrophotometers, mass spectrometers, gas chromatographs, potentiometric titrators, ion analyzers, polarographs, coulometers, x-ray spectro-meters, Karl Fischer titrators, atomic absorption spectrometers, fluorimeters and many, many others.