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Isomeric products are obtained in some addition reactions due to the different possible orientations and arrangements of atoms around the reaction center. For instance, in reactions involving alkenes, the addition of reagents can lead to different stereochemical configurations, such as cis and trans isomers or different chiral centers. Additionally, the presence of multiple reaction pathways can result in varying regioselectivity, leading to structural isomers. These factors contribute to the formation of a mixture of isomeric products.

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