Atom sublevels fill according to the Aufbau principle which states that electron levels are filled according to their energy, the lowest are filled first, then followed by higher energies. To answer your question, 4s has a lower energy level than 3d.
A full electron configuration:
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s6 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p6
Actually the above answer is incorrect and so is the question.
Contrary to what is stated in the vast majority of textbooks, the 4s orbital does not fill before the 3d, and nor does it have lower energy.
If you have access to the Journal of Chemical Education look for the article by Eugen Schwarz. April 2010, p. 444.
eric scerri PhD
UCLA
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The first element that has enough electrons to begin placing in the 3d sublevel is scandium (Sc), which has an atomic number of 21. In its electron configuration, scandium is represented as [Ar] 3d¹ 4s², indicating that the 3d sublevel starts to fill after the 4s sublevel.
Electrons fill the 4s subshell before the 3d subshell. This is due to the Aufbau principle, which states that electrons occupy the lowest energy orbitals first. The 4s orbital has a lower energy level than the 3d orbital when they are both empty, so electrons will fill 4s first. However, once 3d is occupied, it can have a lower energy than 4s when considering additional electrons.
d orbitals begin to fill after the s orbitals of the same principal energy level are filled, specifically starting from the 3d orbitals after the 4s orbital. This occurs due to the energy levels of the orbitals; while the 4s orbital is filled before the 3d, the 3d orbitals have a higher energy level compared to 4s once the 3s and 3p orbitals are filled. As electrons are added to an atom, they occupy the lowest available energy orbitals first, which is why d orbitals fill after the s and p orbitals of the preceding energy level.
The third energy level can have the following electron subshells: 3s, 3p, and 3d.
Electrons occupy orbitals in a definite sequence, filling orbitals with lower energies first. Generally, orbitals in a lower energy level have lower energies than those in a higher energy level. But, in the third level the energy ranges of the principal energy levels begin to overlap. As a result, the 4s sublevel is lower in energy than the 3d sublevel, so it fills first.
4s will fill first because it is at a lower energy level than the 3d level.
There are a maximum of 10 electrons in the 3d sub-level.
The first element that has enough electrons to begin placing in the 3d sublevel is scandium (Sc), which has an atomic number of 21. In its electron configuration, scandium is represented as [Ar] 3d¹ 4s², indicating that the 3d sublevel starts to fill after the 4s sublevel.
Electrons fill the 4s subshell before the 3d subshell. This is due to the Aufbau principle, which states that electrons occupy the lowest energy orbitals first. The 4s orbital has a lower energy level than the 3d orbital when they are both empty, so electrons will fill 4s first. However, once 3d is occupied, it can have a lower energy than 4s when considering additional electrons.
d orbitals begin to fill after the s orbitals of the same principal energy level are filled, specifically starting from the 3d orbitals after the 4s orbital. This occurs due to the energy levels of the orbitals; while the 4s orbital is filled before the 3d, the 3d orbitals have a higher energy level compared to 4s once the 3s and 3p orbitals are filled. As electrons are added to an atom, they occupy the lowest available energy orbitals first, which is why d orbitals fill after the s and p orbitals of the preceding energy level.
A break down of 2d1:2 = the quantum energy level or electron shell denoted as 'n'd = the sub-shell of the energy level (known as a degenerate level)1 = the number of electrons occupying the sub-shell.Through extensive research by scientists, no known element has a d sub-shell in the second (n=2) energy level. In fact, the d sub-shell does not appear until the fourth period (fourth row).The first d sub-shell is known to be in the third energy level (therefore the first energy level with this sub-shell is 3d, but not 2d).Transition metals are the elements known to fill the d sub-shells. The first transition metal in the periodic table is scandium (Sc) with the electron configuration of [Ar]4s23d1.The reasons for the formation of sub-shell of d is beyond my knowledge and the scope of basic chemistry.
There are five different d orbitals within the 3d sublevel: 3dz², 3dxz, 3dyz, 3dx²-y², and 3dxy.
The third energy level can have the following electron subshells: 3s, 3p, and 3d.
Chromium
Electrons occupy orbitals in a definite sequence, filling orbitals with lower energies first. Generally, orbitals in a lower energy level have lower energies than those in a higher energy level. But, in the third level the energy ranges of the principal energy levels begin to overlap. As a result, the 4s sublevel is lower in energy than the 3d sublevel, so it fills first.
The range of the levels is between 0 to n-1. 3 minus 1 equals to 2, so we have 0, 1, 2 as sub levels. They are the same number of sub-levels.
Atomic shorthand uses the noble gas before the element in questionAnswer: Cu: [Ar]4s[1]3d[10]Explanation: Copper Cu is an anomaly. Logically we would write 4s[2]3d[9] but for Cu, having the d sub level full is more stable than having the s sub-shell full and the d sub-shell less than full. Chromium also has this anomaly, and is written [Ar]4s[1]3d[5]