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In luminescence spectroscopy, measurements are taken at right angles to the direction of the incident radiation to minimize the detection of scattered light and enhance the signal from emitted luminescence. This configuration helps to reduce background noise and improves the signal-to-noise ratio, allowing for more accurate measurements of the emitted light. Additionally, it ensures that the detected signal is primarily due to the sample's luminescence rather than reflections or scattering from the excitation source.

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