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The electron configuration of a neutral chromium atom is [Ar]3d54s1. The electron configuration for manganese is [Ar]3d54s2. The first electron removed from a chromium atom is the single 4s electron, leaving the electron configuration [Ar]3d5. The first electron removed from a magnesium atom is one of the 4s2 electrons, leaving the electron configuration [Ar]3d54s1. Removal of a second electron from a chromium atom involves the removal of one of the 3d electrons, leaving a configuration of [Ar]3d4, which is not a very stable configuration, and requires more energy to achieve. Removal of a second electron from a magnesium atom involves the removal of the second 4s electron, leaving a configuration of [Ar]3d5, which is more stable and requires less energy to achieve.

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