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Ion exchange method for the separation of lanthanides?

although the chemical behaviour of all lanthanide ions are almost identical there are slight quantative differences which vary systematically from la to lu . The hydrated radii of ln ions for instance with increase in the atomic number . It is found that the larger the hydrated radius of the ion the less strongly it is bound to the anionic site of an exchange resin . When a solution containing several lanthanides pass slowly through a column of a cation exchange resin the heavier members come through first . The separation can be enhanced by the use of complexing agents like citricacid or citrates. a cation exchange rein like dowex-1 is normally used for adsorption of lanthanide ions . The column is eluted with EDTA . The lanthanides are eluted in the reverse order of their atomic numbers . Polycarboxylates,lactates,hydroxy butyrate and alpha hydroxy carboxylates also can be used as elements . ion exchange method has been used for separation of lanthanides in kilogram quantities for commercial uses


Why are lanthanides difficult to separate?

Lanthanides are difficult to separate because they have very similar chemical properties due to the filling of 4f orbitals, making them hard to distinguish. This similarity makes conventional separation methods less effective, requiring more complex and costly techniques such as solvent extraction or ion exchange to separate them effectively.


What is the difference between lanthanides and actinides?

Wht is the difference between Lanthanides and Actinides?


What about the complex formation ability of lanthanides as campared to actinides?

describe the complex formation by lanthanides?


Are lanthanides radioactive?

Some lanthanides are radioactive, such as promethium. However, most lanthanides found in nature are stable.


Do actinides and lanthanides lose electrons when combining?

Actinides and lanthanides lose electrons and form cations.


What is the group number for Lanthanides and Actinides?

Rare Earth elements or lanthanides are placed in the period 6 of the periodic table of Mendeleev. Actinoids are placed in the period 7 of the periodic table of Mendeleev.


What are the elements of 4F series called?

The elements of the 4f series are called lanthanides. They are a group of metallic elements that have similar properties and occupy the f-block of the periodic table.


Where are the lanthanides?

They are located in the f-block


What is the state of matter for lanthanides?

Lanthanides exist as solids at room temperature and pressure. They have metallic properties and are typically soft, malleable, and ductile.


Are lanthanides gases at room temperature?

No, lanthanides are not gases at room temperature. They are a group of metallic elements that are solid at room temperature.


How variable are the densities of the lanthanides of the lanthanides compared to the densities of the actinides?

The densities of the lanthanides generally have less variability compared to the densities of the actinides. This is because the lanthanides are more similar in size and electronic structure, leading to more consistent densities. In contrast, the actinides exhibit larger variations in density due to differences in atomic structure and electron configurations.