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The electron affinity, or EA, of nitrogen is less than zero (EA = -7) because of is electron configuration, which is [He] 2s2 2p3. Nitrogen, as a neutral atom has a half-filled p-orbital, and by Hund's Rule, that means that each p-orbital has 1 unpaired electron. In the same way that a completely filled orbital is especially stable (like the noble gases), a half-filled orbital IN A NITROGEN ATOM IS HIGHLY UNSTABLE ([He] 2s2 2p4).

In contrast, carbon, C, has a much larger electron affinity (EA = -123.4 kJ/mol) because it has electron configuration [He] 2s2 2p2, which means that the addition of one more electron will bring it to an extra stable half-filled shell. Fluorine of course has an extremely high electron affinity (EA = -331.4 kJ/mol) because of it's electron configuration, [He] 2s2 2p5, where the addition of one more electron gives it a completely filled valence shell or noble gas configuration, [He] 2s2 sp6.

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