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Yes - it's due to the wax the rubber is treated with to protect them. The rubber will, essentially, "sweat" out the wax, leaving a white residue on the boot.

Certain conditions can cause the boots / rubber to sweat more than normal. Below is a link to a step by step guide to removing the white wax bloom residue from a hunter rain boot (but will essentially work with any rain boot). It covers removing the bloom and shining them so that they look brand new.

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