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Atoms are always without charge because this is the 'ground' state of any atomic element. The number of electrons equals the number of protons, so there is NO net charge.

When electrons are gained (eg. by Cl2) or donated (eg. by Na) the compound can be formed by the newly formed ions (Cl- and Na+ will combine to NaCl)

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Related Questions

What is an atom or a group of atoms having a net electrical charge?

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