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Partial molar free energy is the thermodynamic quantity, which indicates how the properties of a mixture vary with changes to their molecular composition, when being kept at a constant temperature and pressure.

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What is the mathematical expression for the first law of thermodynamics?

Partial molar gibbs free energy is actually a derivative or infinitesimal change in molar gibbs free energy wrt an infinitesimal change in mols of that particular component it is also known as the chemical potential (greek letter mu). This is not particularly applicable/useful for pure components but when dealing with mixtures and chemical reactions it can be so it is often given a subscript denoting the species/component it is referring to. Initially many people would not believe it to be any different than the molar gibbs free energy but it is mainly due to two things 1) Entropic effects and 2) Structural and or Chemical non-idealities. So in effect partial molar gibbs free energy is equal to the following expression: (Molar Gibbs free energy)+(Entropic contribution)+(Chemical non-ideality). Molar Gibbs free energy is for a pure component and i will denote it G. Entropic contribution can be derived from further study of thermodynamics is the Universal Gas Constant (R) times the Temperature in Kelvin (T) times the natural logarithm of the mol fraction (ln(x)). Chemical non-ideality is generally given the term excess gibbs free energy (GEX) which has to do with the way in which molecules of the various components interact for instance non-polar molecules with polar molecules and it is modeled in many different ways some of which have advantages over others and studying more advanced thermodynamics will give one more insight into this. The overall expression thus becomes G+RT(ln(x))+GEX.


Is the molar kinetic energy of chlorine gas equal to greater to or less than the molar kinetic energy of nitrogen at 25 degrees Celsius?

The molar kinetic energy of chlorine gas is equal to the molar kinetic energy of nitrogen gas at 25 degrees Celsius. Temperature is the only factor that determines the average kinetic energy of gas particles, not the type of gas.


How is the h fusion used to calculate the mass of a solid that 1 kj of energy will melt?

The enthalpy of fusion (ΔH fusion) is the amount of energy required to melt one mole of a solid at its melting point. To calculate the mass of a solid that 1 kJ of energy will melt, you can use the equation: mass = energy (in kJ) / enthalpy of fusion (in kJ/mol). It gives you the mass of the substance in moles, which you can then convert to grams using the molar mass of the substance.


How much can energy is released when 6.0 g of water is condensed from water vapor?

The energy released when water is condensed from water vapor is known as the heat of condensation. This process releases about 40.7 kJ of energy per mole of water condensed. To calculate the energy released when 6.0 g of water is condensed, you would first convert grams to moles and then use the molar heat of condensation to find the total energy released.


How many moles are in 42 grams of CO2?

To calculate the number of moles in 42 grams of CO2, we first need to find the molar mass of CO2, which is approximately 44 grams per mole. Then, divide the given mass by the molar mass to find the number of moles. In this case, 42 grams of CO2 is equivalent to 42/44 = 0.955 moles.

Related Questions

Partial molar property and its applications?

Partial molar properties are useful thermodynamic properties because their molar average equals the property itself. In this article, we present a description of partial properties in general, and we show that for many partial properties, partial molar properties being a subset, the property is a molar average of the partial properties. Although partial molar properties remain the most useful, several of the other partial properties could have practical applications. © 2009 American Institute of Chemical Engineers AIChE J, 2009


Do they make a partial for one back molar tooth?

no


What are the basic mixing rule?

The basic mixing rule states that the partial molar properties of a mixture can be calculated as the weighted sum of the pure components' properties, using the mole fractions of each component. This rule applies to extensive properties like volume, Gibbs free energy, and entropy. It forms the basis for understanding mixing behavior in solutions and mixtures.


How do you convert energy transferred per gram into energy transferred per mole?

To convert energy transferred per gram to energy transferred per mole, you need to first calculate the molar mass of the substance in grams per mole. Then, you can use this molar mass to convert the energy transferred per gram to energy transferred per mole by multiplying or dividing accordingly.


What is the difference between partial molal quantities and partial molar quantities?

During the determination of the partial molal quantities the weight of the solution to which a substance is added is taken into consideration while in case of the partial molar quantity the volume is taken into consideration.


What is the mathematical expression for the first law of thermodynamics?

Partial molar gibbs free energy is actually a derivative or infinitesimal change in molar gibbs free energy wrt an infinitesimal change in mols of that particular component it is also known as the chemical potential (greek letter mu). This is not particularly applicable/useful for pure components but when dealing with mixtures and chemical reactions it can be so it is often given a subscript denoting the species/component it is referring to. Initially many people would not believe it to be any different than the molar gibbs free energy but it is mainly due to two things 1) Entropic effects and 2) Structural and or Chemical non-idealities. So in effect partial molar gibbs free energy is equal to the following expression: (Molar Gibbs free energy)+(Entropic contribution)+(Chemical non-ideality). Molar Gibbs free energy is for a pure component and i will denote it G. Entropic contribution can be derived from further study of thermodynamics is the Universal Gas Constant (R) times the Temperature in Kelvin (T) times the natural logarithm of the mol fraction (ln(x)). Chemical non-ideality is generally given the term excess gibbs free energy (GEX) which has to do with the way in which molecules of the various components interact for instance non-polar molecules with polar molecules and it is modeled in many different ways some of which have advantages over others and studying more advanced thermodynamics will give one more insight into this. The overall expression thus becomes G+RT(ln(x))+GEX.


How do you calculate the molar volume of a substance?

To calculate the molar volume of a substance, you divide the volume of the substance by the number of moles present. This can be done using the formula: Molar Volume Volume / Number of Moles.


What is molar polarisation?

Molar polarisation is the separation of positive and negative charges within a molecule or ion due to differences in electronegativity or other factors. This can result in a molecule having a partial positive and partial negative charge, making it polar.


How do you calculate molar susceptibility from momentum?

neon


How is stoichiometry used to calculate energy absorbed when a mass melts?

Stoichiometry can be used to calculate the energy absorbed when a mass melts by considering the enthalpy of fusion, which is the amount of energy required to change a substance from solid to liquid at its melting point. By using the molar mass of the substance and the enthalpy of fusion, you can calculate the amount of energy needed to melt a specific mass of the substance.


What are the key differences between molar pregnancy partial vs complete, and how do they impact the diagnosis and treatment of this condition?

Molar pregnancy is a rare condition where abnormal tissue grows in the uterus instead of a normal pregnancy. The key difference between partial and complete molar pregnancies lies in the genetic makeup of the abnormal tissue. In partial molar pregnancies, there is an abnormal fetus with some normal placental tissue, while in complete molar pregnancies, there is no fetus and all the tissue is abnormal. Diagnosis of molar pregnancy is typically done through ultrasound and blood tests to measure hormone levels. Treatment usually involves removing the abnormal tissue through a procedure called dilation and curettage (DC). In complete molar pregnancies, there is a higher risk of complications such as persistent trophoblastic disease, which may require additional treatment like chemotherapy. Partial molar pregnancies have a lower risk of complications compared to complete molar pregnancies.


How do you calculate the percentage of water in a hydrate?

To calculate the percentage of water in a hydrate, you first determine the molar mass of the water and the compound. Then, you divide the molar mass of the water by the molar mass of the hydrate and multiply by 100 to get the percentage.