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The atoms in a solid are arranged in closely packed. Lot of energy is required to break the bond between atoms or molecules. Supplied energy to the solid is loose in the form of vibrations. They vibrate back and forth, but do not (inter)change place, so there is no molecular 'velocity'. Liquids and gases even more have 'speady' molecules (that's why those material states don't have a certain 'shape').

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