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Motion of the vessel (pouring) or irregularities around the mouth initiate a radial motion. If air enters the vessel, the increased flow sends the liquid further out (inertial forces against the neck of the vessel) and a vortex can build up.

(Do not get fooled into thinking the Coriolis effect has anything to do with it- the Coriolis effect only plays a part in very large systems such as weather patterns)

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