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That depends entirely on which Union County you are requesting information about. There are seventeen Union Counties in various states across the US. According to census.gov, the 2007 estimated total population of each of these Union Counties and which state they are located in are listed alphabetically as follows:

# Union County, Arkansas: 43,230 # Union County, Florida: 14,991 # Union County, Georgia: 20,968 # Union County, Illinois: 18,257 # Union County, Indiana: 7,203 # Union County, Iowa: 12,146 # Union County, Kentucky: 15,092 # Union County, Mississippi: 26,907# Union County, New Jersey: 524,658 # Union County, New Mexico: 3,792 # Union County, North Carolina: 184,675# Union County, Ohio: 47,234 # Union County, Oregon: 24,753 # Union County, Pennsylvania: 43,724 # Union County, South Carolina: 27,770 # Union County, South Dakota: 13,952 # Union County, Tennessee: 18,877

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