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To unlock Luigi you must complete the first stage of adventure mode with a time of xx:x2:xx, then complete the remainder of adventure mode. You will fight Luigi at the end of the adventure mode. Defeat Luigi and he will become a playable character.
You can also unlock Luigi by playing 800 versus mode battles. The winner of the 800th game will be challenged by Luigi. Defeat Luigi and he will become a playbale character.
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