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No. The .22 is smaller in diameter than the .25 and would be too small for the chamber of a .25. Generally speaking, you should never try to fire any cartridge in any handgun other than what it is designed to fire. While it may be possible to get a cartridge to fire from a different gun, it may cause damage to the gun or the shooter. Additionally, I forgot to mention that the .22 is a rimfire cartridge and the .25 is a center fire, the the firing mechanism is slightly different in the two guns.

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