When was the first Muzzle loading rifle invented?

Answer 1

The origins of rifling are difficult to trace, but some of the earliest practical experiments seem to have occurred in Europe during the fifteenth century. Archers had long realized that a twist added to the tail feathers of their arrows gave them greater accuracy. Early muskets produced large quantities of smoke and soot, which had to be cleaned from the action and bore of the musket frequently; either the action of repeated bore scrubbing, or a deliberate attempt to create "soot grooves" might also have led to a perceived increase in accuracy, although no one knows for sure. True rifling dates from the mid-15th century, although the precision required for its effective manufacture kept it out of the hands of infantrymen for another three and a half centuries, when it largely replaced the unrifled musket as the primary infantry weapon. In the transitional nineteenth century, the term "rifled musket" was used to indicate the novel weapon. During the Napoleonic Wars the British army created several experimental units known as "Rifles", armed with the Baker rifle. These Rifle Regiments were deployed as skirmishers during the Peninsular war in Spain and Portugal, and were more effective than skirmishers armed with muskets due to their accuracy and long range.

For more:

* http://en.wikipedia.org/wiki/Rifle