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You can use denatured alcohol to check to see if latex paint is on the wall. Rub a rag moistened with denatured alcohol onto the surface. If the paint melts and is removed by the rag, you have latex. If it just cleans the area, then it is probably oil. It could also be epoxy or xylene based, but that is rarely done in a residential application other than flooring.

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Q: How do you know if walls were painted with oil or water paint?
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