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The geometry for SF6 is octahedral, with a central sulfur atom surrounded by 6 equidistant fluorine atoms situated in the following way:

One on the positive x-axis, one on the negative x-axis, one on the positive y-axis, one on the negative y-axis, one on the positive z-axis, and one on the negative z-axis.

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Q: What is the electron-pair geometry for S in SF6?
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SF6 is non-polar. Reason: Fluorine is more electronegative than sulfur, so the bond dipoles point toward fluorine. However, all the six S-F bonds are arranged octahedrally around the central sulfur. F F \ / F-S-F / \ F F Because the octahedral geometry is symmetrical, the bond dipoles cancel each other, and the molecule is nonpolar, meaning that µ = 0. Source: Another Qs from the same topic (SF6 from wikiANSWERS) which quotes the source as: "Straight from Chemistry: The Central Science. 11e. Brown/LeMay/Bursten/Murphy"


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Is SF6 polar or nonpolar?

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What is the chemical name for compound SF6?

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