Because of the mechanism of addition polymerization;
In addition polymerization the pi-bond of a molecule with a double bond (e.g. ethene) is broken by attatchment of a radical (a molecule with a lone electron) to the molecule with the double bond:
one of the two electrons that formed the double bond pairs up with the single electron from the radical so the other electron from the double bond becomes a lone electron himself; and so it continues until two radicals meet each other.
So you need to have a double bond in order to have this kind of polymerization;
(there are other kinds of polymerization of molecules whitch have a functional group but ethane nor ethene has these so it doesn't apply to them.)
why addition reaction take place in ethene and ethyne but not in ethane
double bond
The plastic poly [ethene ]- polyethylene is formed.
number of carbon atoms
Ethyne is most reactive where as ethane is least.
prepare ethane from ethene
Both ethene and ethane contain two carbons. Ethene has a double bond between its two carbons while ethane has a single bond. Because of this, ethane contains six hydrogen atoms, but ethene only contains four.
ethene is a gas
It is done by the process of Hydrogenation. Example:- C2H4 + H2 ---------> C2H6 Thus, ethene undergoes hydrogenation to form ethane
double bond
ethene
Combustion.
This the simultaneous polymerization of ethene and propylene.
The plastic poly [ethene ]- polyethylene is formed.
number of carbon atoms
Ethyne is most reactive where as ethane is least.
You think probable to polymerization.
You are trying to reduce ethane to ethene, I am guessing. That is a very hard reaction to do... probably you will have to do a free radical halogenation on ethane to form 1-chloroethane, followed by an E2 reaction with t-butoxide or some other bulky base to form ethene. Since ethane and ethene are both gases and cheaply available from petroleum cracking, this reaction really isn't worth doing.