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When looking at potassium and bromine, it would seem that with more electrons occupying more orbitals, bromine would be larger. However, in addition to those additional electrons, bromine also has additional protons. These protons in the nucleus pull on all of bromine's electrons with more strength than the nucleus of potassium, and the stronger pull offsets any size gained by adding electrons.

In short, bromine's nucleus pulls harder.

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Q: Why does potassium have a larger atomic radius than bromine?
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