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Alessandro Volta

, Inventor / Physicist

  • Born: 18 February 1745
  • Birthplace: Como, Italy (then Lombardy)
  • Died: 5 March 1827
  • Best Known As: The Italian who built the first battery

Count Alessandro Giuseppe Antonio Anastasio Volta was the Italian physicist who built the first electrochemical battery. He first gained fame across Europe in 1775 with his electrophorus, a charge-generating machine he built while teaching physics in his hometown of Como. He was appointed to the University of Pavia in 1779, where he continued his work with static electricity and built a number of gadgets. Volta's debate with anatomist Luigi Galvani about the nature of electricity in organic tissue (what Galvani called "animal electricity") caused him to experiment with metal plates, and in 1800 he succeeded in creating a sustained flow of electricity with his "voltaic pile," a stack of metal plates in a salt solution. The invention made Volta even more famous and he was called to France by Napoleon in 1801 to receive the first of many honors and decorations. (Napoleon made him Count Volta in 1810.) The unit of measurement of electromotive force is called the volt in his honor and was adopted internationally in 1881.

 
 
Scientist: Volta, Alessandro Giuseppe Antonio Anastasio, Count

[b. Como, (Italy), February 18, 1745, d. Como, March 5, 1827]

Volta is remembered for his invention in 1799 of the first electric battery, chemically producing an electric current with plates of two different metals soaking in brine. About 25 years earlier, Volta invented the electrophorus, a device for creating large amounts of static electricity still used today. In 1778 he was the first to isolate the gas methane (CH4).


 
Biography: Alessandro Volta

The Italian physicist Alessandro Volta (1745-1827) invented the electric battery, or "voltaic pile," thus providing for the first time a sustained source of current electricity.

Alessandro Volta was born on Feb. 18, 1745, in Como. He resisted pressure from his family to enter the priesthood and developed instead an intense curiosity about natural phenomena, in particular, electricity. In 1769 he published his first paper on electricity. It contained no new discoveries but is of some interest as the most speculative of all Volta's papers, his subsequent ones being devoted almost exclusively to the presentation of specific experimental discoveries.

Early Investigations and Inventions

In 1774 Volta was appointed professor of physics at the gymnasium in Como, and that same year he made his first important contribution to the science of electricity, the invention of the electrophorus, a device which provided a source of electric potential utilizing the principle of electrostatic induction. Unlike earlier source of electric potential, such as the Leyden jar, the electrophorus provided a sustained, easily replenishable source of static electricity. In 1782 Volta announced the application of the electrophorus to the detection of minute electrical charges. His invention of the so-called condensing electroscope culminated his efforts to improve the sensitivity of earlier electrometers.

During these same years Volta also conducted researches of a purely chemical nature. He had for some time been experimenting with exploding various gases, such as hydrogen, in closed containers and had observed that when hydrogen and air were exploded there was a diminution in volume greater than the volume of hydrogen burned. In order to measure such changes in volume, he developed a graduated glass container, now known as a eudiometer, in which to explode the gases. Utilizing this eudiometer he studied marsh gas, or methane, and distinguished it from hydrogen by its different-colored flame, its slower rate of combustion, and the greater volume of air and larger electric spark required for detonation.

In 1779 Volta was appointed to the newly created chair of physics at the University of Pavia. In 1782 he became a corresponding member of the French Academy of Sciences. In 1791 he was elected a fellow of the Royal Society of London, and in 1794, in recognition of his contributions to electricity and chemistry, he was awarded the society's coveted Copley Medal. However, his most significant researches - those which were to lead to the discovery of current electricity - were yet to be undertaken.

Discovery of Current Electricity

Until the last decade of the 18th century electrical researchers had been primarily concerned with static electricity, with the electrification produced by friction. Then, in 1786, Luigi Galvani discovered that the muscles in a frog's amputated leg would contract whenever an electrical machine was discharged near the leg. As a result of his initial observations, Galvani undertook a long series of experiments in an effort to more thoroughly examine this startling phenomenon. In the course of these investigations he discovered that a frog's prepared leg could be made to contract if he merely attached a copper hook to the nerve ending and then pressed the hook against an iron plate on which the leg was resting so as to complete an electrical circuit, even though no electrical machines were operating in the vicinity. Galvani concluded the contraction was produced in the organism itself and referred to this new type of electricity as "animal electricity."

Galvani's experiments and interpretation were summarized in a paper published in 1791, a copy of which he sent to Volta. Although, like most others, initially convinced by Galvani's arguments, Volta gradually came to the conclusion that the two metals were not merely conductors but actually generated the electricity themselves. He began by repeating and verifying Galvani's experiments but quickly moved beyond these to experiments of his own, concentrating on the results of bringing into contact two dissimilar metals. By 1794 he had convinced himself that the metals, in his own words, "are in a real sense the exciters of electricity, while the nerves themselves are passive," and he henceforth referred to this new type of electricity as "metallic" or "contact" electricity.

The announcement of Volta's experiments and interpretation touched off one of the great controversies in the history of science. Although other factors were important as well, the physiologists and anatomists tended to support Galvani's view that the electricity was produced by the animal tissue itself whereas the physicists and chemists, like Volta, tended to see it as produced by the external bimetallic contacts. The resulting rivalry not only took on international dimensions but died out only gradually after more than a decade. Although Galvani withdrew from the arena, allowing others to carry his standard, Volta took an active role in the controversy and vigorously pursued his research.

Volta discovered that not only would two dissimilar metals in contact produce a small electrical effect, but metals in contact with certain types of fluids would also produce such effects. In fact, the best results were obtained when two dissimilar metals were held in contact and joined by a moist third body which, in modern terminology, completed the circuit between them. Such observations led directly to the construction in 1800 of the electric battery, or "pile" as Volta called it, the first source of a significant electric current.

Volta announced his discovery in a letter to Sir Joseph Banks, then president of the Royal Society of London. The letter, dated March 20, 1800, created an instant sensation. Here for the first time was an instrument capable of producing a steady, continuous flow of electricity. All previous electrical machines, including Volta's electrophorus, had produced only short bursts of static electricity. The ability to create at will a sustained electrical current opened vast new fields for investigation, and the significance of Volta's discovery was immediately recognized.

Acclaim and Retirement

Volta was summoned to Paris by Napoleon and in 1801 gave a series of lectures on his discoveries before the National Institute of France, as the Academy of Sciences was then called. A special gold medal was struck to honor the occasion, and the following year Volta was distinguished by election as one of the eight foreign associates of the institute.

Although only in his mid-50s when he announced the discovery of the "pile," Volta took no part in applying his discovery to any of the immense new fields it opened up. During the last 25 years of his life he demonstrated none of the intense creativity that had characterized his earlier researches, and he published nothing of scientific significance during these later years. He continued, at the urging of Napoleon, to teach at the University of Pavia and eventually became director of the philosophy faculty there. In 1819 he retired to his family home near Como. He died there on March 5, 1827, little realizing that current electricity would eventually transform a way of life.

Further Reading

Recommended for further details on Volta is the excellent brief treatment in Bern Dibner, Alessandro Volta and the Electric Battery (1964). A good historical account of the beginning of the age of electricity is in F. Sherwood Taylor, A Short History of Science and Scientific Thought (1949), and Bern Dibner, Galvani-Volta: A Controversy That Led to the Discovery of Useful Electricity (1952).

 
Britannica Concise Encyclopedia: Alessandro Giuseppe Antonio Anastasio Volta

(born Feb. 18, 1745, Como, Lombardy — died March 5, 1827, Como) Italian scientist. In 1775 he invented the electrophorus, a device used to generate static electricity. He taught physics at the University of Pavia (1779 – 1804). After Luigi Galvani in 1780 produced an electric current by connecting two different metals with the muscle of a frog, Volta began experimenting in 1794 with metals alone and found that animal tissue was not needed to produce current. He demonstrated the first electric battery in 1800. In 1801 he demonstrated the battery's generation of current before Napoleon, who made him a count and senator of the kingdom of Lombardy. In 1815 he was appointed director of the philosophical faculty at the University of Padua. The volt was named in his honour in 1881.

For more information on Alessandro Giuseppe Antonio Anastasio Volta, visit Britannica.com.

 
Columbia Encyclopedia: Volta, Alessandro, Conte
(älĕs-sän'drō kôn'tā vôl') , 1745–1827, Italian physicist. He was professor of physics at the Univ. of Pavia from 1779 and became famous for his work in electricity. Napoleon I made him a count and a senator of the kingdom of Lombardy. Volta invented the so-called Volta's pile (or voltaic pile); the electrophorus; an electric condenser; and the voltaic cell. The volt, a unit of electrical measurement, is named for Volta.
 
Wikipedia: Alessandro Volta
Alessandro Volta
Alessandro_Volta.jpeg
Alessandro Giuseppe Antonio Anastasio Volta (1745-1827)
Born February 18 1745(1745--)
Como-Stemma.png Como, Lombardy, Italy
Died March 5 1827 (aged 82)
Como-Stemma.png Como, Lombardy, Italy
Residence Flag_of_Italy.svg Italy
Nationality Flag_of_Italy.svg Italian
Field Physicist
Known for Development of the electric battery

Count Alessandro Giuseppe Antonio Anastasio Volta (February 18, 1745 - March 5, 1827) was an Italian physicist known especially for the development of the electric battery in 1800.

Career

In 1774, he became professor of physics in the Como high school. His passion had always been the study of electricity, and while still a young student he had even written a poem in Latin on this fascinating new discovery. His first scientific paper he titled De vi attractiva ignis electrici ac phaenomenis inde pendentibus.

De vi attractiva ....
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De vi attractiva ....

Inventions and discoveries

In 1775 he invented the electrophorus, a device that produced a static electric charge. In 1776-77 he studied the chemistry of gases, discovered methane, and devised experiments such as the ignition of gases by an electric spark in a closed vessel. Volta also studied what we now call capacitance, developing separate means to study both electrical potential V and charge Q, and to discovering that for a given object they are proportional. This may be called Volta's Law of Capacitance, and likely for this work the unit of electrical potential has been named the volt. In 1779 he became professor of experimental physics at the University of Pavia, a chair he occupied for almost 40 years. In 1794, Volta married the daughter of Count Ludovico Peregrini, Teresa, with whom he raised three sons. Each of his three sons went on to improve on the Voltaic Pile in ways that all ended in strait ends.

Around 1791 he began to study the "animal electricity" noted by Galvani when two different metals were connected in series with the frog's leg and to one another. He realized that the frog's leg served as both a conductor of electricity (we would now call it an electrolyte) and as a detector of electricity. He replaced the frog's leg by brine-soaked paper, and detected the flow of electricity by other means familiar to him from his previous studies of electricity. In this way he discovered the electrochemical series, and the law that the electromotive force (emf) of a galvanic cell, consisting of a pair of metal electrodes separated by electrolyte, is the difference of their two electrode potentials. That is, if the electrodes have emfs \mathcal{E}_{1,2}, then the net emf is \mathcal{E}_{2}-\mathcal{E}_{1}. (Thus, two identical electrodes and a common electrolyte give zero net emf.) This may be called Volta's Law of the electrochemical series.

In 1800, as the result of a professional disagreement over the galvanic response advocated by Luigi Galvani, he invented the voltaic pile, an early electric battery, which produced a steady electric current. Volta had determined that the most effective pair of dissimilar metals to produce electricity was zinc and silver. Initially he experimented with individual cells in series, each cell being a wine goblet filled with brine into which the two dissimilar electrodes were dipped. The electric pile replaced the goblets with cardboard soaked in brine. (The number of cells, and thus the voltage it could produce, was limited by the pressure, exerted by the upper cells, that would squeeze all of the brine out of the cardboard of the bottom cell.)

In announcing his discovery of the pile, Volta paid tribute to the influences of William Nicholson, Tiberius Cavallo and Abraham Bennet.[1]

The Voltaic battery

The battery made by Volta is credited to have been the first cell. It consists of two electrodes: one made of zinc, the other of copper. The electrolyte is sulphuric acid. The electrolyte exists in the form 2H+ and SO4 2-. The zinc, which is higher than both copper and hydrogen in the electrochemical series, reacts with the negatively charged sulphate. ( SO4 ) The positively charged hydrogen bubbles start depositing around the copper and take away some of its electrons. This makes the zinc rod the negative electrode and the copper rod the positive electrode.

We now have 2 terminals, and the current will flow if we connect them. The reactions in this cell are as follows:

The zinc Zn -> Zn2+ + 2e-
The copper Cu -> Cu2+ + 2e-
The sulphuric acid H2SO4 -> H2 + SO4

However, this cell also has some disadvantages. It is unsafe to handle, as sulphuric acid, even if dilute, is dangerous. Also, the potential difference in the terminals finishes after some time. So it is not durable, and therefore, not a suitable choice.

Honours

In honour of his work in the field of electricity, Napoleon made him a count in 1810; in 1815 the Emperor of Austria named him a professor of philosophy at Padua.

Before 1796, Lombardy was ruled by Austria. From 1796 to 1815, Lombardy came under Napoleon's rule. After 1815, Lombardy was once again under Austrian rule. Thus Volta was once a subject of the Emperor of Austria, later a subject of Napoleon and then later a subject of the Emperor of Austria again.[2]

The Tempio Voltiano, Como
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The Tempio Voltiano, Como

He was a long-time correspondent of the Royal Society and was made a fellow (FRS). He received the Society's 1794 Copley Medal. He published his invention of the Voltaic pile battery in 1800 in the Philosophical Transactions of the Royal Society. He was in correspondence with scientists in Austria, which ruled Lombardy in his day, and inm France: in fact his 1800 paper was written in French.

Volta is buried in the city of Como; the Tempio Voltiano near Lake Como there is a museum devoted to explaining his work; his original instruments and papers are on display there. The building appeared, along with his portrait, on Italian 10.000 lira banknote, before the introduction of the euro.

In 1881 an important electrical unit, the volt, was named in his honor. The Toyota Alessandro Volta is named after Volta. Volta Crater on the Moon is also named after him.

Retirement

Volta entered retirement in Spain.

References

  1. ^ *Elliott, P. (1999). "Abraham Bennet F.R.S. (1749-1799): a provincial electrician in eighteenth-century England" (PDF). Notes and Records of the Royal Society of London 53(1): 59-78.  (
  2. ^ Giuliano Pancaldi, "Volta: Science and culture in the age of enlightenment", Princeton University Press, 2003.

External links

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Awards
Preceded by
Benjamin Thompson
Copley Medal
1794
Succeeded by
Jesse Ramsden


Persondata
NAME Volta, Alessandro
ALTERNATIVE NAMES
SHORT DESCRIPTION Physicist
DATE OF BIRTH February 18 1745(1745--)
PLACE OF BIRTH Como, Lombardy, Italy
DATE OF DEATH March 5 1827
PLACE OF DEATH Como, Lombardy, Italy

 
 

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Who2 Biography. Copyright © 1998-2008 by Who2, LLC. All rights reserved. See the Alessandro Volta biography from Who2.  Read more
Scientist. History of Science and Technology, edited by Bryan Bunch and Alexander Hellemans. Copyright © 2004 by Houghton Mifflin Company. Published by Houghton Mifflin Company. All rights reserved.  Read more
Biography. © 2006 through a partnership of Answers Corporation. All rights reserved.  Read more
Britannica Concise Encyclopedia. Britannica Concise Encyclopedia. © 2006 Encyclopædia Britannica, Inc. All rights reserved.  Read more
Columbia Encyclopedia. The Columbia Electronic Encyclopedia, Sixth Edition Copyright © 2003, Columbia University Press. Licensed from Columbia University Press. All rights reserved. www.cc.columbia.edu/cu/cup/  Read more
Wikipedia. This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Alessandro Volta" Read more

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