Radiometric titration is "regular" titration, but with the
incorporation of a radioactive indicator to monitor the end-point.
And that's right from the IUPAC Compendium of Chemical Terminology.
If you need an example, use the link provided to a post on the
radiometric titration of hexachloro-platinate (IV). It's a bit
esoteric, but it will serve to exemplify the idea behind
radiometric titration. It's pretty clear that when working with two
precipitates (co-precipitation), the analyst would need a way to
differentiate them. In the case cited, the application of
radioactive cæsium-137 will permit the observer to more quickly and
easily find a cutoff point at which to terminate the titration.