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The original air in the tire is old and weak so new air pumped in is stronger because it's newer and faster ;) Just kidding, really though the pressure of the air in the tire compared to the pressure of the air applied to the valve stem is the determining factor to whether or not you will be pumping air in the tire or letting it out of the tire. 10psi in the tire and 20psi at the air chuck equals a 10psi difference, and if the air chuck is applied to the valve stem the tire will fill with 10psi more of air and will then equal 20psi in the tire if the 20psi air pressure can be maintained at the fill chuck by an air compressor. Why, because different pressures will want to equal themselves to each other if they are aloud to occupy the same area with the higher pressure always wanting to expand into the lower pressure area, like inside a tire.

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Q: Additional air can be pump into the tire filled with air because?
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