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At first one has to suppose that the concentrations of HA and HB are the same! 1)

Eq.P. at pH=8: You need less OH- (titrant) to reach this, so the acid donated its last proton easier, so it was stronger. (Eq.P. at pH=7 means it isn't weak at all)

1) It is more accurate to compare pH value's half-the-wayof titration, because pH1/2way is exactly equal to pKa value of the acid concerned AND it is independent of concentration: it is buffered!!!

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Q: At the equivalence point if pH of HA is 8 and the pH of HB is 9 which is the stronger acid?
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A 0.361 molar solution of the weak acid HA with a pKa of 4.039 is titrated with a 0.163 molar solution of NaOH. What is the pH of the solution at the equivalence point of this titration?

You need to know the volume of the weak acid being titrated so you can find how many moles of base are needed to match that of the acid.


At the equivalence point if pH of HA is 8 and the pH of HB is 9 which is the stronger acid Also which conjugate base would be stronger A or B?

Conjugate base B- is stronger, it has a higher pH at Eq.P.Your first (and also the original) question is answered as follows:At first one has to suppose that the concentrations of HA and HB are the same! 1)Eq.P. at pH=8: You need less OH- (titrant) to reach this, so the acid donated its last proton easier, so it was stronger. (Eq.P. at pH=7 means it isn't weak at all)1) It is more accurate to compare pH value's half-the-wayof titration, because pH1/2way is exactly equal to pKa value of the acid concerned AND it is independent of concentration: it is buffered!!!


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