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If the car is a Flex-Fuel vehicle then yes you can use E85. If it is not a Flex-Fuel vehicle you cannot use E85. Using E85 will damage components. As far as I know your 2006 Pontiac G6 is not a Flex-Fuel vehicle. Reads your owner's manual to be sure.

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Q: Can e85 fuel be used in your 2006 Pontiac G6?
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