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Yes, It is a natural phenomomena.

It can be recorded in the layers of ice at the poles and traced back many thousands of years.

It follows natural cycles of the sun and emmisions from volcanos.

It has also been suggested that changes in tempeature, Follow changes in CO2 and not vice versa, which is the more popular guess.

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Q: Does the CO2 levels of the earths armosphere change?
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