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The question should be (I guess)..."Which would have a greater emulsifying power in 'hard' water, soaps or detergents?". The answer to that question is certainly the detergent. (Further, fyi, shampoos are great emulsifiers in hard water compared with the two.)

*Please see molecular structures of soaps and detergents to understand how and why detergents emulsify more than soaps.

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Q: Does the hard water have a greater emulsifying power than soap or deterget yes or no?
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