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They don't, they actually have a greater tendency to lose electrons.

This is for a number of reasons.

First of all, the alkali metals form a stable cation by losing one electron, while the alkaline-earth metals need to lose two to form a stable ion. It takes more energy to remove one electron from an atom than it does to remove two.

Additionally an alkaline earth metal has a greater positive charge on its nucleus and a smaller atomic radius than an alkali metal in the same row of the Periodic Table. This make it even harder to remove valence electrons.

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?? WRONG: Alkali metals have a valence electron configuration of ns1 so they can accept another electron in the ns orbital. On the other hand, alkaline earth metals have a valence electron configuration of ns2. Alkaline earth metals have little tendency to accept another electron, as it woudl have to go into a higher energy p orbital.

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Q: Explain why alkali metals have a greater affinity for electrons than alkaline earth metals?
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