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The electron shells are filled in order 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p. Ground state just means the energy level that electron normally inhabits ie its shell. Electrons can be promoted to higher energy levels if the atom absorbs light energy and then the atom will emit that energy as the electrons fall back to their normal state.

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Q: Ground state of a 3 d electron?
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