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Coolant does break down. Depending on how bad it is and what type of engine it's in it can even become acidic. That's usually in a diesel engine though. It is recommended to change the antifreeze every 50,000 or so. It does keep the water pump and other cooling system seals lubed.

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Q: Heard of radiator fluid decaying or destroying the seals in an auto engine the mechanic said that old fluid will destroy the seals and then destroy your engine?
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