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Your best option would be to first completely strip the wheels of all old paint and rust, then go from there. First use a light coloured primer coat (two coats would be preferable), then you can use whichever paint you'd like - it doesn't necessarily have to be automotive paint, and you could even 'spray bomb' them, if you wished.

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Q: How do i go about re-painting old slightly rusty steel wheels not alloys and do you need to remove all old paint etc?
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