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Most greenhouses are well vented. They have fans and vents that suck out old air, or blow in the new. The trick is cold weather, if you're in an arctic envoronment (Alaska) you may have to have the air that's going into the greenhosue heated. The best way to do this and create the new CO2 is to have some kind of gas heater in an enclosure, that both heats the air and creates the CO2. It is better to avoid that, if the air outside isn't freezing, because those systems are expensive.

The best way is to use proper ventilation to the outdoors, while finding a way to keep your inside temperature stable.

There are systems in scientific studies that use canisters of compressed CO2. This would not, however, be aplicable to a greenhouse.

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Q: How do people get the extra CO2 into their greenhouses?
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