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The net heating value will considering the evaporation of water formed in reaction of natural gas decomposition as follow

CnHm+(n+m/4)O2=nO2+m/2H2O

For Methane : CH4 we have

n=1 " number of carbon

m=4 " number of hydrogen

then: CH4+(1+4/2)O2

O2+2H2O=CH4+3O2=2H2O

Subtracting enthalpy of products from reactants to get enthalpy of decomposition

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Q: How do you calculate heating value of natural gas?
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