Sulphuric Acid requires, I believe 27.2ml to make a 1N solution.
Potassium acid phthalate is a common primary standard used to standardize bases. Obviously, it would depend upon how much NaCl was present, but the end result will be to reduce the amount of available H+ for the mass of KHP-NaCl mixture. That would cause you to understate the concentration of the base.
The reasons KHP is used as a primary standard are as follows: (1) It is not hydroscopic, (2) it has a high molecular weight, so a reasonable amount to titrate can be easily weighed, and (3) it is stable at temperatures over 100°C so that any water may be driven off by heating.
KHC8H4O4(aq) + NaOH(aq) --> KNaC8H4O4(aq) + H2O(l). The molar mass of KHP is approximately 204.22 g/mol. 1.54g of KHP is equivalent to 0.00754 mol of KHP. 1 mole of NaOH reacts per mole of KHP, so .00754 mol of NaOH are needed.
71.0800g/mole
sodium hydroxide is a secondary standard because it absorb the moisture from the air and its concentration will change
Sulphuric Acid requires, I believe 27.2ml to make a 1N solution.
Potassium acid phthalate is a common primary standard used to standardize bases. Obviously, it would depend upon how much NaCl was present, but the end result will be to reduce the amount of available H+ for the mass of KHP-NaCl mixture. That would cause you to understate the concentration of the base.
The reasons KHP is used as a primary standard are as follows: (1) It is not hydroscopic, (2) it has a high molecular weight, so a reasonable amount to titrate can be easily weighed, and (3) it is stable at temperatures over 100°C so that any water may be driven off by heating.
KHC8H4O4(aq) + NaOH(aq) --> KNaC8H4O4(aq) + H2O(l). The molar mass of KHP is approximately 204.22 g/mol. 1.54g of KHP is equivalent to 0.00754 mol of KHP. 1 mole of NaOH reacts per mole of KHP, so .00754 mol of NaOH are needed.
Since KHP is an unknown (name for a) chemical compound the molarity can not be calculated by lack of data.The molar mass (m) of KHP ANDthe number (n) of H+ per mol KHP (maybe 1 when monoprotic?) is necessary for calculation, according to this formula:(M*V)NaOH = (n*mass/m)KHPso:[OH-] (mol.L-1) * 0.02850 (L NaOH sol'n) = n (mol H+.mol-1 KHP) * 0.7154 (g KHP) / m (g.mol-1 KHP)
molar mass of KHP is 204.2g/mole. the formula for KHP is C8H5O4K therefore, (12.01*8)+(1.008*5)+(16*4)+39.1 = 204.2g/mol
71.0800g/mole
Potassium Hydrogen Phthalate
KHC8H4O4(aq) + NaOH(aq) → KNaC8H4O4(aq) + H2O(l) NaOH(aq) + KHP(aq) => Na+ + KP- + H2O(l)
1/1n
KHP