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This is because in the presence of air chloroform is oxidised to phosgene. To prevent the formation of phosgene, they are stored in dark colored bottles.
CHCl3 + 1/2 O2 ---->HCl + COCl2.

Phosgene is represented as COCl2. This is poisonous.

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Q: How do you test the purity of a sample of chloroform?
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