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The crystal structure of frozen water the commonly occurring "hexagonal" form, "Ice one" consists of oxygen atoms surrounded by 4 hydrogen atoms. the OH bond angle is tetrahedral but two atoms are closer at 101 pm (in molecular water they are slightly closer at around 98pm.) The bonding is therefore best described as two covalent and two hydrogen bonds.

This is a rather open structure and the oxygen atoms are further apart in the solid than they are on average in the liquid. This explains why ice is not as dense as liquid water and therefore floats. Ice that forms quickly is amorphous with only short range ordering.

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Q: How does hydrogen bonding affect the volume of frozen water and why?
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Hydrogen bonding !


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