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Every 100 grams (100 millilitres) of boiling water (even hard water) will dissolve a maximum of about 40 grams of salt, so anything in excess of that amount just will not dissolve. If your poured a teaspoon of salt grains into a pan of boiling water it would dissolve immediately - almost no time at all.

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Q: How much time does salt take to dissolve in hard boiled water?
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