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Oxygen and nitrogen are in the same period of the table, and within a period, atomic radius decreases with increasing atomic number. Oxygen has a higher atomic number than nitrogen. From the Periodic Table alone, there is no direct information about the size of the molecules, but both these elements form diatomic molecules, and it is reasonable that molecules formed from the same number of atoms will have sizes in the same order as the sizes of the atoms.

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Q: How would you know from looking at the periodic table that O molecules are smaller than nitrogen molecules?
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