neg, neg, less
APEX :)
If the sign of ΔH is _______ and the sign of ΔS is _______ , then the magnitude of TΔS must be ________ than the magnitude of ΔH for the reaction to be spontaneous. The Gibbs free energy equation is ΔG = ΔH - TΔS. negative; negative; less
For a redox reaction to be spontaneous, the standard cell potential (cell) must be positive.
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΔG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΔS term outweighs the positive ΔH term, resulting in a negative ΔG. This means the reaction will be spontaneous at elevated temperatures.
The enthalpy change for the reverse reaction is equal in magnitude but opposite in sign to the enthalpy change for the forward reaction.
Endothermic and exothermic reactions have the same magnitude of energy change but are opposite in sign. In an endothermic reaction, energy is absorbed from the surroundings, while in an exothermic reaction, energy is released to the surroundings.
Sign . . . negative Magnitude . . . 33
Reversing the equation gives the oxidation half reaction. Doing this changes the sign on the voltage, not the magnitude.
The name of the single thermodynamic quantity is Gibbs free energy (G). The symbol for Gibbs free energy is ΔG (delta G). The sign of ΔG determines whether a reaction is spontaneous (negative ΔG) or non-spontaneous (positive ΔG).
Dissolving calcium chloride in water is not so spontaneous.
The unit of Gibbs free energy, which is joules (J), is used to measure the amount of energy available to do work in a chemical reaction. The spontaneity of a chemical reaction is determined by the sign of the Gibbs free energy change (G). If G is negative, the reaction is spontaneous and can occur without external intervention. If G is positive, the reaction is non-spontaneous and requires external energy input to proceed.
The change in Gibbs Free Energy (∆Gº) predicts if a reaction is spontaneous or not. The equation for this is ∆G = ∆H - T∆S where ∆H is the change in enthalpy, T is temperature in Kelvin, and ∆S in change in entropy.
If you need to reverse a reaction and multiply it by 2 in Hess's law, the enthalpy change of the reaction will also change sign and double in magnitude. This is because reversing a reaction changes the sign of the enthalpy change. Multiplying the reaction by a factor also multiplies the enthalpy change by that factor. Therefore, the final value for the enthalpy of the reaction will be twice the original magnitude but with the opposite sign.