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Yes it is. From the definition of steam distillation we can know that the components of the distillation are immiscible and one of the components is water. Since water's boiling point is 100'C, boiling point of the mixture must be less than that.

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Q: Is the boiling point of steam distillation involving two immiscible components always less than 100?
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How do you sperate two immiscible liquids?

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