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I am not aware of a process that can convert these compounds into methane. However I have read of an article where developement of a solar cell that generates electricity through some mechanism of reacting carbon dioxide and water to generate methanol. It may not be methane but methanol in of itself is also valuable as a fuel and to generate electricity through a byproduct is just astounding.

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Q: Is there any possibility for coversion of CO2 and H2O produced from combustion in automobiles into CH4?
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