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Q: What are the mechanism of chelate formation?
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What chelate is formed by lead and dithiozone?

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How come chelation is related with entropy 'gain'?

Not chelation, but chelate effect can be explained predominantly with entropy factor. Chelate effect describes about enhanced affinity of chelating ligands for a metal ion in comparison to the affinity of a collection of similar non chelating (monodentate) ligands for the same metal. So, when we compare the 2 cases we observe that the entropy factor favours the chelate formation because the reactants were lesser (because of polydenticity). I hope you got your answer.


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