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I hope this is not a valid question. And I really don't see how it could be. Such a mixture would prove fatal, unless you mean a very small portion. How would a child get this substance? No one should be ingesting such a lethal combination. I just don't get it. One thing that is very likely with even a small amount would be permanent damage to the kidneys and liver.

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She did become very sick & was taken to the hospital.

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The main long term effect of this behavior would be death. Period. Rubbing alcohol is a form of alcohol that is quite poisonous. Nasty flavoring that is also an emetic is added, so that people will use it as rubbing alcohol and not a cocktail. Blindness is one common result of drinking it. Death is another. For a child, any use of alcohol is not a good idea, in my opinion. Vodka in sufficient quantity can kill, just like any other form of alcohol. How a child got their hands on vodka, and rubbing alcohol, and became motivated to mix them and drink them, is a question that should be directed to local law enforcement. This child is clearly not in a safe environment.

that could be deadly

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Q: What are the possible long-term effects on a child who drank rubbing alcohol mixed with vodka?
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