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You are asking for two liquids that share the same boiling point and dissolve in each other? The best I could find so far are allyl alcohol (97.2 C) and propyl alcohol (97.5 C). There are probably other liquids (especially organic) out there that share closer boiling points.

I also found that the elements erbium (atomic number 68) and terbium (atomic number 65) share the same boiling point--3230 C. They may or may not be miscible. I guess it's hard to tell at that temperature.

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Q: What are the two miscible liquids having same boiling point?
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For basic idea, different liquid had different boiling point thus upon boiling the vapour would contain more of the lower boiling point and separated out.


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