Hitsugaya did not beat Tōsen; it was Hisagi. This occurred in episode 291 "Desperate Struggle with Aizen! Hirako, Shikai!"
not in 9tail form
go to http://www.animeseason.com/skip-beat-episode-18/
48 49 and 50
126.
Not sure when it was made but the last episode of Skip Beat to air was March 30, 2009 according to AniDB.net
Episode 68 (part 2)
Episode 3x01, The Purple Piano Project
in the episode where she beat up heue
its not out yet
By flying
Ash beats Paul in the episode that is titled "Battling a Thaw in Relations."
The name of the episode is called, "Eat to the Beat".