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Are you talking about the plant or the pepper itself? Either way, this is often a sign of a nutrient deficiency. If its the pepper itself, I'd say its likely to be blossom end rot, which means a calcium deficiency. If its the stems of the plant, its probably either a potassium or a phosphorus deficiency (the P and the K in NPK). Take a sample of the problem to a nearby nursery -- a real one, not a Home Depot -- and they can help you diagnose the problem.
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