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CaCO3(s)+2NaOH(aq)--->Ca(OH)2(aq)+Na2CO3(aq)

When you heat it later, the water in the solution evaporates leaving you with just the salts.

Also, it is better to say, calcium carbonate is added to sodium hydroxide solution as you add a solid to a solution not really vice versa.

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Q: What happens when sodium hydroxide solution is added to calcium carbonate and then warmed?
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