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A ligand exchange reaction is exactly what it says - a reaction in which one ligand in a complex ion is replaced by a different one. When a precipitate is formed in a solution, the solution remains a saturated solution of the compound. In other words, cations and anions of the compound remain in the solution. The cations are usually hydrated; that is, water molecules are 'ligands' and are attached to the cations by dative bonds. If some substance is added that can form even stronger bonds with the cations than water, the water molecules(or some part of them) are replaced by the new ligand, and the concentration of the hydrated ion drops. hi sammi

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Q: What is the definition of ligand exchange?
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