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Let's break this down into simple thermodynamics. If you have a gun, and it constantly overheats, it's going to need a radiator/heatsink on it. Still with me? Once you have appropriately determined if said weapon needs cooling, you need to then decide what type. Air flow will dissipate heat off of a hot barrel. Kind of similar to the "blow on soup to cool it off"-method. Still with me? Another way is to submerge said barrel in a water tank. The water is colder than the barrel is and will draw heat away from the barrel. Hence heating the water up. This works similar to most vehicles, but instead of water they use coolant (neon green).

In simple terms, you answered your own question.

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Q: What is the difference between air cool and water cool?
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